skip to main content
Language:
Search Limited to: Search Limited to: Resource type Show Results with: Show Results with: Search type Index

Formation of Single-Bonded (C60 -)2 and (C70 -)2 Dimers in Crystalline Ionic Complexes of Fullerenes

Journal of the American Chemical Society, 2003-08, Vol.125 (33), p.10074-10083 [Peer Reviewed Journal]

Copyright © 2003 American Chemical Society ;ISSN: 0002-7863 ;EISSN: 1520-5126 ;DOI: 10.1021/ja035546a ;PMID: 12914471

Full text available

Citations Cited by
  • Title:
    Formation of Single-Bonded (C60 -)2 and (C70 -)2 Dimers in Crystalline Ionic Complexes of Fullerenes
  • Author: Konarev, Dmitri V ; Khasanov, Salavat S ; Saito, Gunzi ; Otsuka, Akihiro ; Yoshida, Yukihiro ; Lyubovskaya, Rimma N
  • Is Part Of: Journal of the American Chemical Society, 2003-08, Vol.125 (33), p.10074-10083
  • Description: New ionic complexes of fullerenes C60 and C70 with decamethylchromocene Cp*2Cr·C60· (C6H4Cl2)2 (1), Cp*2Cr·C60·(C6H6)2 (2); the multicomponent complex of (Cs+)(C70 -) with cyclotriveratrylene CTV·(Cs)2·(C70)2·(DMF)7·(C6H6)0.75 (3); bis(benzene)chromium Cr(C6H6)2·C60·(C6H4Cl2)0.7 (4), Cr(C6H6)2·C60·C6H5CN (5), Cr(C6H6)2·C70·C6H4Cl2 (6), Cr(C6H6)2·C60 (7); cobaltocene Cp2Co·C60·C6H4Cl2 (8), Cp2Co·C70·(C6H4Cl2)0.5 (9); and cesium Cs·C70·(DMF)5 (10) have been obtained. The complexes have been characterized by the elemental analysis, IR-, UV−vis−NIR spectroscopy, EPR and SQUID measurements. It is shown that C60 •- exists as a single-bonded diamagnetic (C60 -)2 dimer in 1, 2, 4, 5, and 8 at low temperatures (1.9−250 K). The dimers dissociate above 160−250 K depending on donor and solvent molecules involved in the complex. C60 •- dimerizes reversibly and shows a small hysteresis (<2 K) at slow cooling and heating rates. The single-bonded diamagnetic (C70 -)2 dimers are also formed in 6, 9, and 10 and begin to dissociate only above 250−360 K. The IR and UV−vis−NIR spectra of σ-bonded negatively charged fullerenes are presented.
  • Publisher: United States: American Chemical Society
  • Language: English
  • Identifier: ISSN: 0002-7863
    EISSN: 1520-5126
    DOI: 10.1021/ja035546a
    PMID: 12914471
  • Source: Alma/SFX Local Collection
Back to results list
INSPIRE LIBRARY - TON DUC THANG UNIVERSITY (84-028) 37 755 057 Feedback
19 Nguyen Huu Tho St. Dist.7, HCM thuvien@tdtu.edu.vn

Copyright © 2017 INSPIRE LIBRARY - TON DUC THANG UNIVERSITY

Searching Remote Databases, Please Wait