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Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer

Nature communications, 2020-02, Vol.11 (1), p.944-944, Article 944 [Peer Reviewed Journal]

This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. ;The Author(s) 2020 ;ISSN: 2041-1723 ;EISSN: 2041-1723 ;DOI: 10.1038/s41467-020-14792-1 ;PMID: 32071308

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  • Title:
    Color-tunable ultralong organic room temperature phosphorescence from a multicomponent copolymer
  • Author: Gu, Long ; Wu, Hongwei ; Ma, Huili ; Ye, Wenpeng ; Jia, Wenyong ; Wang, He ; Chen, Hongzhong ; Zhang, Nan ; Wang, Dongdong ; Qian, Cheng ; An, Zhongfu ; Huang, Wei ; Zhao, Yanli
  • Subjects: Color ; Copolymerization ; Crosslinking ; Electronics ; Emission ; Emissions ; Encryption ; Functional materials ; Luminescence ; Phosphorescence ; Polymers ; Room temperature
  • Is Part Of: Nature communications, 2020-02, Vol.11 (1), p.944-944, Article 944
  • Description: Functional materials displaying tunable emission and long-lived luminescence have recently emerged as a powerful tool for applications in information encryption, organic electronics and bioelectronics. Herein, we present a design strategy to achieve color-tunable ultralong organic room temperature phosphorescence (UOP) in polymers through radical multicomponent cross-linked copolymerization. Our experiments reveal that by changing the excitation wavelength from 254 to 370 nm, these polymers display multicolor luminescence spanning from blue to yellow with a long-lived lifetime of 1.2 s and a maximum phosphorescence quantum yield of 37.5% under ambient conditions. Moreover, we explore the application of these polymers in multilevel information encryption based on the color-tunable UOP property. This strategy paves the way for the development of multicolor bio-labels and smart luminescent materials with long-lived emission at room temperature.
  • Publisher: England: Nature Publishing Group
  • Language: English
  • Identifier: ISSN: 2041-1723
    EISSN: 2041-1723
    DOI: 10.1038/s41467-020-14792-1
    PMID: 32071308
  • Source: PubMed Central
    ProQuest Central
    DOAJ Directory of Open Access Journals

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