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Experimental, computational analysis of Butein and Lanceoletin for natural dye-sensitized solar cells and stabilizing efficiency by IoT

Environment, development and sustainability, 2022-06, Vol.24 (6), p.8807-8822 [Peer Reviewed Journal]

The Author(s), under exclusive licence to Springer Nature B.V. 2021 ;The Author(s), under exclusive licence to Springer Nature B.V. 2021. ;ISSN: 1387-585X ;EISSN: 1573-2975 ;DOI: 10.1007/s10668-021-01810-5

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Title:
Experimental, computational analysis of Butein and Lanceoletin for natural dye-sensitized solar cells and stabilizing efficiency by IoT
Author: Bradha, M. ; Balakrishnan, Nagaraj ; Suvitha, A. ; Arumanayagam, T. ; Rekha, M. ; Vivek, P. ; Ajay, P. ; Sangeetha, V. ; Steephen, Ananth
Subjects: Anodes ; Butea ; Chemical reactions ; Chemicals ; Coloring agents ; Competence ; Computer applications ; Density ; Dye-sensitized solar cells ; Dyes ; Earth and Environmental Science ; Ecology ; Economic Geology ; Economic Growth ; Electrostatic properties ; Energy conversion ; Energy industry ; Energy storage ; Environment ; Environmental Economics ; Environmental Management ; Industrial Internet of Things for Intelligent Transportation System to Decrease the Environmental Pollution ; Internet of Things ; Molecular orbitals ; Molecular structure ; Nonlinear response ; Petals ; Photosensitivity ; Photovoltaic cells ; Reactivity ; Refilling ; Renewable energy ; Softness ; Solar cells ; Sustainable Development ; Titanium dioxide
Is Part Of: Environment, development and sustainability, 2022-06, Vol.24 (6), p.8807-8822
Description: The thoughtful implementation of Internet of Things (IoT) expertise to sustainable progress in environment friendly renewable energy sector is significant for future energy conversion, storage and usage. The exploration of IoT proficiency in restoring the fresh condition of natural dye-sensitized solar cells once again by refilling the photo-sensitizer from its dye-degraded condition is conceived. This concept will eliminate one of the key limitations of dye-sensitized solar cells in real-world application. Potential environment friendly organic dyes were separated from the Butea Monosperma petals and employed for proficient titanium dioxide (TiO 2 ) photo-anodes. Butein and Lanceoletin are prominent colorants existent in the organic source (Butea Monosperma petals) and enhanced molecular structures premeditated. The colorant-sensitized TiO 2 NPs underwent the structural, photosensitive, spectral and IV (current–voltage) readings. Comparative DFT (density functional theoretical) and experimental studies on the spectroscopic, electronic and nonlinear opto-response characteristics of Butein and Lanceoletin were performed. The change in HOMO–LUMO energy which governs kinetic steadiness, chemical reactivity, chemical softness, hardness and MEP (molecular electrostatic potential) of molecules has been intended at B3LYP@6-311G (d, p). Environment friendly, price-effective NDSSCs were made by using organic photo-anodes. Graphic abstract
Publisher: Dordrecht: Springer Netherlands
Language: English
Identifier: ISSN: 1387-585X
EISSN: 1573-2975
DOI: 10.1007/s10668-021-01810-5
Source: ProQuest Central

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Experimental, computational analysis of Butein and Lanceoletin for natural dye-sensitized solar cells and stabilizing efficiency by IoT

The Author(s), under exclusive licence to Springer Nature B.V. 2021 ;The Author(s), under exclusive licence to Springer Nature B.V. 2021. ;ISSN: 1387-585X ;EISSN: 1573-2975 ;DOI: 10.1007/s10668-021-01810-5

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