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The MoMo Quintuple Bond as a Ligand to Stabilize Transition-Metal Complexes

Angewandte Chemie (International ed.), 2015-07, Vol.54 (31), p.9106 [Peer Reviewed Journal]

ISSN: 1433-7851 ;EISSN: 1521-3773 ;DOI: 10.1002/anie.201504414 ;CODEN: ACIEAY

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  • Title:
    The MoMo Quintuple Bond as a Ligand to Stabilize Transition-Metal Complexes
  • Author: Lu, Duan-Yen ; Chen, Peter P-Y ; Kuo, Ting-Shen ; Tsai, Yi-Chou
  • Subjects: Chemical bonds
  • Is Part Of: Angewandte Chemie (International ed.), 2015-07, Vol.54 (31), p.9106
  • Description:   Herein, we report the employment of the MoMo quintuple bonded amidinate complex to stabilize Group10 metal fragments {(Et3P)2M} (M=Pd, Pt) and give rise to the isolation of the unprecedented [delta]complexes. X-ray analysis unambiguously revealed short contacts between Pd or Pt and two Mo atoms and a slight elongation of the MoMo quintuple bond in these two compounds. Computational studies show donation of the MoMo quintuple-bond [delta]electrons to an empty σorbital on Pd or Pt, and back-donation from a filled Pd or Pt dπ orbital into the MoMo [delta]*level (LUMO), consistent with the Dewar-Chatt-Duncanson model.
  • Publisher: Weinheim: Wiley Subscription Services, Inc
  • Language: English
  • Identifier: ISSN: 1433-7851
    EISSN: 1521-3773
    DOI: 10.1002/anie.201504414
    CODEN: ACIEAY
  • Source: Alma/SFX Local Collection
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