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Preparations of Itrans/I- and Icis/I-Iμ/I-1,2-Peroxodiiron Complexes

Molecules (Basel, Switzerland), 2023-12, Vol.29 (1) [Peer Reviewed Journal]

COPYRIGHT 2023 MDPI AG ;ISSN: 1420-3049 ;EISSN: 1420-3049 ;DOI: 10.3390/molecules29010205

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  • Title:
    Preparations of Itrans/I- and Icis/I-Iμ/I-1,2-Peroxodiiron Complexes
  • Author: Kajita, Yuji ; Kubo, Masaki ; Arii, Hidekazu ; Ishikawa, Shinya ; Saito, Yamato ; Wasada-Tsutsui, Yuko ; Funahashi, Yasuhiro ; Ozawa, Tomohiro ; Masuda, Hideki
  • Subjects: Instrument industry
  • Is Part Of: Molecules (Basel, Switzerland), 2023-12, Vol.29 (1)
  • Description: The iron(II) complex with cis,cis-1,3,5-tris(benzylamino)cyclohexane (Bn[sub.3]CY) (1) has been synthesized and characterized, which reacted with dioxygen to form the peroxo complex 2 in acetone at −60 °C. On the basis of spectroscopic measurements for 2, it was confirmed that the peroxo complex 2 has a trans-μ-1,2 fashion. Additionally, the peroxo complex 2 was reacted with benzoate anion as a bridging agent to give a peroxo complex 3. The results of resonance Raman and [sup.1]H-NMR studies supported that the peroxo complex 3 is a cis-μ-1,2-peroxodiiron(III) complex. These spectral features were interpreted by using DFT calculations.
  • Publisher: MDPI AG
  • Language: English
  • Identifier: ISSN: 1420-3049
    EISSN: 1420-3049
    DOI: 10.3390/molecules29010205
  • Source: Geneva Foundation Free Medical Journals at publisher websites
    AUTh Library subscriptions: ProQuest Central
    PubMed Central
    Alma/SFX Local Collection
    DOAJ Directory of Open Access Journals
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