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The chemical oxidation of lignin found in Sappi Saiccor dissolving pulp mill effluent

Water S. A., 2012-01, Vol.38 (1), p.1-8 [Peer Reviewed Journal]

Copyright Water Research Commission Jan 2012 ;This work is licensed under a Creative Commons Attribution 4.0 International License. ;ISSN: 0378-4738 ;ISSN: 1816-7950 ;EISSN: 0378-4738 ;EISSN: 1816-7950 ;DOI: 10.4314/wsa.v38i1.1

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  • Title:
    The chemical oxidation of lignin found in Sappi Saiccor dissolving pulp mill effluent
  • Author: Moodley, B. ; Mulholland, D.A. ; Mulholland, D.A. ; Brookes, H.C.
  • Subjects: Byproducts ; Chemical oxidation ; Dissolution ; Effluent ; Effluents ; Eucalyptus ; Hydrogen ; Hydrogen peroxide ; Lignin ; Mills ; Nitrobenzenes ; Oxidation ; Pulp & paper mills ; Syringaldehyde ; Vanillin ; Water Resources
  • Is Part Of: Water S. A., 2012-01, Vol.38 (1), p.1-8
  • Description: Sappi Saiccor (situated in Durban, South Africa) dissolving pulp mill effluent, produced from an acid bisulphite pulping process, uses acacia and eucalyptus hardwoods to produce a unique and different blend of lignin that has not been previously studied. The chemical oxidation of lignin found in Sappi Saiccor's effluent has been investigated using a number of different chemical oxidising agents, such as nitrobenzene, oxygen with and without the presence of a copper sulphate pentahydrate catalyst, and hydrogen peroxide. The reaction products were extracted with acid and identified using GC-MSand LC-MS techniques. Nitrobenzene is a good oxidising agent but tends to produce many toxic by-products and would not be acceptable on an industrial scale. Oxygen oxidation has previously been shown to produce aldehyde-type compounds, and in this work has produced good yields of both vanillin and syringaldehyde compared to previous oxygen oxidation reactions. Hydrogen peroxide is a strong oxidising agent that tends to over-oxidise the lignin during long reaction times.
  • Publisher: Gezina: Water Research Commission (WRC)
  • Language: English;Portuguese
  • Identifier: ISSN: 0378-4738
    ISSN: 1816-7950
    EISSN: 0378-4738
    EISSN: 1816-7950
    DOI: 10.4314/wsa.v38i1.1
  • Source: Open Access: DOAJ Directory of Open Access Journals
    Sabinet African Journals Open Access Collection
    Open Access: African Journals Online
    SciELO
    Geneva Foundation Free Medical Journals at publisher websites
    AUTh Library subscriptions: ProQuest Central

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