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Flexible supercapacitor electrodes based on real metal-like cellulose papers

Nature communications, 2017-09, Vol.8 (1), p.536-11, Article 536 [Peer Reviewed Journal]

2017. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. ;The Author(s) 2017 ;ISSN: 2041-1723 ;EISSN: 2041-1723 ;DOI: 10.1038/s41467-017-00550-3 ;PMID: 28912562

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  • Title:
    Flexible supercapacitor electrodes based on real metal-like cellulose papers
  • Author: Ko, Yongmin ; Kwon, Minseong ; Bae, Wan Ki ; Lee, Byeongyong ; Lee, Seung Woo ; Cho, Jinhan
  • Subjects: Accumulators ; Assembly ; Capacitance ; Cellulose ; Charge materials ; Collectors ; Contact resistance ; Electrodes ; Energy storage ; Flux density ; Implantation ; Ligands ; Maximum power ; Metals ; Nanoparticles ; Organic chemistry ; Supercapacitors ; Wearable technology
  • Is Part Of: Nature communications, 2017-09, Vol.8 (1), p.536-11, Article 536
  • Description: The effective implantation of conductive and charge storage materials into flexible frames has been strongly demanded for the development of flexible supercapacitors. Here, we introduce metallic cellulose paper-based supercapacitor electrodes with excellent energy storage performance by minimizing the contact resistance between neighboring metal and/or metal oxide nanoparticles using an assembly approach, called ligand-mediated layer-by-layer assembly. This approach can convert the insulating paper to the highly porous metallic paper with large surface areas that can function as current collectors and nanoparticle reservoirs for supercapacitor electrodes. Moreover, we demonstrate that the alternating structure design of the metal and pseudocapacitive nanoparticles on the metallic papers can remarkably increase the areal capacitance and rate capability with a notable decrease in the internal resistance. The maximum power and energy density of the metallic paper-based supercapacitors are estimated to be 15.1 mW cm and 267.3 μWh cm , respectively, substantially outperforming the performance of conventional paper or textile-type supercapacitors.With ligand-mediated layer-by-layer assembly between metal nanoparticles and small organic molecules, the authors prepare metallic paper electrodes for supercapacitors with high power and energy densities. This approach could be extended to various electrodes for portable/wearable electronics.
  • Publisher: England: Nature Publishing Group
  • Language: English
  • Identifier: ISSN: 2041-1723
    EISSN: 2041-1723
    DOI: 10.1038/s41467-017-00550-3
    PMID: 28912562
  • Source: PubMed Central
    ProQuest Central
    DOAJ Directory of Open Access Journals

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