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The Influence of Organofunctional Substituents of Spherosilicates on the Functional Properties of PLA/TiO[sub.2] Composites Used in 3D Printing

Polymers, 2022-12, Vol.14 (24) [Peer Reviewed Journal]

COPYRIGHT 2022 MDPI AG ;ISSN: 2073-4360 ;EISSN: 2073-4360 ;DOI: 10.3390/polym14245493

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  • Title:
    The Influence of Organofunctional Substituents of Spherosilicates on the Functional Properties of PLA/TiO[sub.2] Composites Used in 3D Printing
  • Author: Sztorch, Bogna ; Pakuła, Daria ; Kustosz, Magdalena ; Romanczuk-Ruszuk, Eliza ; Gabriel, Ewa ; Przekop, Robert E
  • Subjects: 3D printing ; Analysis
  • Is Part Of: Polymers, 2022-12, Vol.14 (24)
  • Description: In this study, the influence of TiO[sub.2] pigment filler modified with spherosilicate derivatives on the processes and thermomechanical properties of composites based on PLA was investigated. Rheological tests (MFR) were carried out, on the basis of which it was found that the addition of organosilicon compounds has a plasticizing effect on the polymer-filler systems. TGA and DSC analysis were performed. The analysis of the contact angle showed that 1.5% of the additives had an influence on the superhydrophobic properties of TiO[sub.2] (above 135°), and a slight improvement of this parameter was also observed for composites containing the modified pigment. Microscopic analysis and mechanical tests (tensile strength, impact strength and flexural strength tests) were carried out as well. It has been observed that the addition of certain derivatives adversely affects the dispersion of the filler, thus a slight improvement in mechanical properties is observed. For modifiers that do not affect filler agglomeration, a plasticizing effect on the composite is observed.
  • Publisher: MDPI AG
  • Language: English
  • Identifier: ISSN: 2073-4360
    EISSN: 2073-4360
    DOI: 10.3390/polym14245493
  • Source: Geneva Foundation Free Medical Journals at publisher websites
    PubMed Central
    Directory of Open Access Journals
    ROAD: Directory of Open Access Scholarly Resources
    ProQuest Central
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