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Novel NHC-Based Au Nuggets under Oxidative Conditions
Molecules (Basel, Switzerland), 2023-03, Vol.28 (5)
[Peer Reviewed Journal]
COPYRIGHT 2023 MDPI AG ;ISSN: 1420-3049 ;EISSN: 1420-3049 ;DOI: 10.3390/molecules28052302
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Title:
Novel NHC-Based Au Nuggets under Oxidative Conditions
Author:
Font, Pau
;
Tzouras, Nikolaos V
;
Papastavrou, Argyro T
;
Vougioukalakis, Georgios C
;
Ribas, Xavi
Subjects:
Catalysis
;
Chemical properties
;
Jewelry
Is Part Of:
Molecules (Basel, Switzerland), 2023-03, Vol.28 (5)
Description:
The Lewis-acidic character and robustness of NHC-Au(I) complexes enable them to catalyze a large number of reactions, and they are enthroned as the catalysts of choice for many transformations among polyunsaturated substrates. More recently, Au(I)/Au(III) catalysis has been explored either by utilizing external oxidants or by seeking oxidative addition processes with catalysts featuring pendant coordinating groups. Herein, we describe the synthesis and characterization of N-heterocyclic carbene (NHC)-based Au(I) complexes, with and without pendant coordinating groups, and their reactivity in the presence of different oxidants. We demonstrate that when using iodosylbenzene-type oxidants, the NHC ligand undergoes oxidation to afford the corresponding NHC=O azolone products concomitantly with quantitative gold recovery in the form of Au(0) nuggets ~0.5 mm in size. The latter were characterized by SEM and EDX-SEM showing purities above 90%. This study shows that NHC-Au complexes can follow decomposition pathways under certain experimental conditions, thus challenging the believed robustness of the NHC-Au bond and providing a novel methodology to produce Au(0) nuggets.
Publisher:
MDPI AG
Language:
English
Identifier:
ISSN: 1420-3049
EISSN: 1420-3049
DOI: 10.3390/molecules28052302
Source:
Open Access: DOAJ Directory of Open Access Journals
Open Access: PubMed Central
Geneva Foundation Free Medical Journals at publisher websites
AUTh Library subscriptions: ProQuest Central
Alma/SFX Local Collection
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