skip to main content
Language:
Search Limited to: Search Limited to: Resource type Show Results with: Show Results with: Search type Index

Transition-Metal-Catalyzed π-Bond-Assisted CH Bond Functionalization: An Emerging Trend in Organic Synthesis

Chemistry, an Asian journal, 2015-04, Vol.10 (4), p.824-838 [Peer Reviewed Journal]

2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim ;2015 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. ;ISSN: 1861-4728 ;EISSN: 1861-471X ;DOI: 10.1002/asia.201403224 ;PMID: 25581838

Full text available

Citations Cited by
  • Title:
    Transition-Metal-Catalyzed π-Bond-Assisted CH Bond Functionalization: An Emerging Trend in Organic Synthesis
  • Author: Gandeepan, Parthasarathy ; Cheng, Chien-Hong
  • Subjects: annulation ; CH activation ; directing groups ; homogeneous catalysis ; transition metals
  • Is Part Of: Chemistry, an Asian journal, 2015-04, Vol.10 (4), p.824-838
  • Description: Transition‐metal‐catalyzed CH activation is considered to be an important tool in organic synthesis and has been accepted and widely used by chemists because it is straightforward, cost‐effective, and environmentally friendly. A variety of functional groups have been used to direct metal complexes and achieve regioselective CH activation. Most directing is achieved through the σ‐bond coordination of functional groups to the metal catalyst, followed by ortho‐selective CH bond cleavage. However, recent work has demonstrated that π‐coordinating functional groups can also assist in guiding metal complexes for site‐selective CH bond activation. This emerging approach significantly expands the scope of CH activation reactions in organic synthesis. Herein, recent developments in this field are summarized. Piece of pi: Transition‐metal‐catalyzed directing‐group‐assisted CH activation reactions play an indispensable role in organic synthesis. Most directing groups interact with metals through the σ coordination of their lone pairs, yet π‐bond directing groups also exist (see figure). The π‐coordination‐assisted CH bond functionalization reactions are summarized.
  • Publisher: Weinheim: WILEY-VCH Verlag
  • Language: English
  • Identifier: ISSN: 1861-4728
    EISSN: 1861-471X
    DOI: 10.1002/asia.201403224
    PMID: 25581838
  • Source: Alma/SFX Local Collection
Back to results list
INSPIRE LIBRARY - TON DUC THANG UNIVERSITY (84-028) 37 755 057 Feedback
19 Nguyen Huu Tho St. Dist.7, HCM thuvien@tdtu.edu.vn

Copyright © 2017 INSPIRE LIBRARY - TON DUC THANG UNIVERSITY

Searching Remote Databases, Please Wait