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para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property

Journal of the American Chemical Society, 2008-04, Vol.130 (15), p.5022-5023 [Peer Reviewed Journal]

Copyright © 2008 American Chemical Society ;ISSN: 0002-7863 ;EISSN: 1520-5126 ;DOI: 10.1021/ja711260m ;PMID: 18357989

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  • Title:
    para-Bridged Symmetrical Pillar[5]arenes: Their Lewis Acid Catalyzed Synthesis and Host–Guest Property
  • Author: Ogoshi, Tomoki ; Kanai, Suguru ; Fujinami, Shuhei ; Yamagishi, Tada-aki ; Nakamoto, Yoshiaki
  • Is Part Of: Journal of the American Chemical Society, 2008-04, Vol.130 (15), p.5022-5023
  • Description: Condensation of 1,4-dimethoxybenzene (DMB) with paraformaldehyde in the presence of BF3·O(C2H5)2 gave novel para-bridged pentacyclic pillar DMB (DMpillar[5]arene). Moreover, para-bridged pentacyclic hydroquinone (pillar[5]arene) was prepared. Pillar[5]arene formed 1:1 host–guest complexes with dialkyl viologen and alkyl pyridinium derivatives. However, pillar[5]arene did not form complexes with the diadamantyl viologen derivative since a bulky adamantyl group was unable to thread the cavity of pillar[5]arene.
  • Publisher: United States: American Chemical Society
  • Language: English
  • Identifier: ISSN: 0002-7863
    EISSN: 1520-5126
    DOI: 10.1021/ja711260m
    PMID: 18357989
  • Source: Alma/SFX Local Collection
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