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Recyclable Polydimethylsiloxane Network Crosslinked by Dynamic Transesterification Reaction

Scientific reports, 2017-09, Vol.7 (1), p.11833-9, Article 11833 [Peer Reviewed Journal]

2017. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License. ;The Author(s) 2017 ;ISSN: 2045-2322 ;EISSN: 2045-2322 ;DOI: 10.1038/s41598-017-11485-6 ;PMID: 28928370

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  • Title:
    Recyclable Polydimethylsiloxane Network Crosslinked by Dynamic Transesterification Reaction
  • Author: Zhang, Huan ; Cai, Chao ; Liu, Wenxing ; Li, Dongdong ; Zhang, Jiawei ; Zhao, Ning ; Xu, Jian
  • Subjects: Elastomers ; Hot pressing ; Mechanical properties ; Plastics ; Polydimethylsiloxane
  • Is Part Of: Scientific reports, 2017-09, Vol.7 (1), p.11833-9, Article 11833
  • Description: This article reports preparation of a crosslinked polydimethylsiloxane (PDMS) network via dynamic transesterification reaction between PDMS-diglycidyl ether and pripol 1017 with Zn(OAc) as the catalyst. The thermal dynamic nature of the network was investigated by the creep-recovery and stress-relaxation tests. The synthesized PDMS elastomer showed excellent solvent resistance even under high temperature, and could be reprocessed by hot pressing at 180 °C with the mechanical properties maintained after 10 cycles. Application of the PDMS elastomer in constructing micro-patterned stamps repeatedly has been demonstrated. The high plastic temperature and good solvent resistance distinguish the research from other reported thermoplastic PDMS elastomers and broaden the practical application areas.
  • Publisher: England: Nature Publishing Group
  • Language: English
  • Identifier: ISSN: 2045-2322
    EISSN: 2045-2322
    DOI: 10.1038/s41598-017-11485-6
    PMID: 28928370
  • Source: PubMed Central
    ProQuest Central
    Directory of Open Access Journals: DOAJ
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