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Carbon-Carbon Bond Cleavage by Strongly Electrophilic Boranes

Chemistry : a European journal, 2010-11, Vol.16 (42), p.12538-12540 [Peer Reviewed Journal]

Copyright © 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim ;ISSN: 0947-6539 ;EISSN: 1521-3765 ;DOI: 10.1002/chem.201002047 ;PMID: 20878812 ;CODEN: CEUJED

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  • Title:
    Carbon-Carbon Bond Cleavage by Strongly Electrophilic Boranes
  • Author: Xu, Bao-Hua ; Kehr, Gerald ; Fröhlich, Roland ; Erker, Gerhard
  • Subjects: boranes ; carboboration ; CC activation ; ring expansion
  • Is Part Of: Chemistry : a European journal, 2010-11, Vol.16 (42), p.12538-12540
  • Description: Make and break: Strongly electrophilic boranes RB(C6F5)2 (R=Me, CH2CH2Ph) react with an aminodihydropentalene substrate by CC bond cleavage with concomitant borylene insertion to yield the ring‐enlarged zwitterionic borate/iminium product.
  • Publisher: Weinheim: WILEY-VCH Verlag
  • Language: English
  • Identifier: ISSN: 0947-6539
    EISSN: 1521-3765
    DOI: 10.1002/chem.201002047
    PMID: 20878812
    CODEN: CEUJED
  • Source: Alma/SFX Local Collection
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