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1,2-Methyl-1,2-Oxaphospholan-5-One 2-Oxide Fire Retardance in HIPS: The Effect of Melamine and Novolac

Journal of fire sciences, 2004-03, Vol.22 (2), p.163-178 [Peer Reviewed Journal]

2004 INIST-CNRS ;ISSN: 0734-9041 ;EISSN: 1530-8049 ;DOI: 10.1177/0734904104039607 ;CODEN: JFSCDV

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  • Title:
    1,2-Methyl-1,2-Oxaphospholan-5-One 2-Oxide Fire Retardance in HIPS: The Effect of Melamine and Novolac
  • Author: Balabanovich, A. I.
  • Subjects: Applied sciences ; Building technical equipments ; Buildings ; Buildings. Public works ; Exact sciences and technology ; Fire behavior of materials and structures ; Fire protection
  • Is Part Of: Journal of fire sciences, 2004-03, Vol.22 (2), p.163-178
  • Description: The effects of commercially available 1,2-methyl-1,2-oxaphospholan-5-one 2-oxide (OP), melamine, and novolac on the limiting oxygen index and UL94 test behavior of high impact polystyrene (HIPS) were studied. A synergistic flame-retardant effect between OP and melamine was observed at the ratio 3: 2 of the additives. Thermogravimetric analysis revealed that charring in the HIPS formulations is mainly caused by an interaction between the additives. The FT-IR study of the OP and melamine-based formulation showed that the charring results in the formation of polyaromatic and polyphosphazene-type structures. The data supporting low temperature decomposition of the symm-triazine ring in the condensed state on pyrolysis are presented.
  • Publisher: Lancaster, PA: SAGE Publications
  • Language: English
  • Identifier: ISSN: 0734-9041
    EISSN: 1530-8049
    DOI: 10.1177/0734904104039607
    CODEN: JFSCDV
  • Source: Alma/SFX Local Collection
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