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Effect of oligosaccharide deposition on the surface of cellulose nanocrystals as a function of acid hydrolysis temperature

Cellulose (London), 2016-12, Vol.23 (6), p.3555-3567 [Peer Reviewed Journal]

Springer Science+Business Media Dordrecht 2016 ;Copyright Springer Science & Business Media 2016 ;Cellulose is a copyright of Springer, (2016). All Rights Reserved. ;ISSN: 0969-0239 ;EISSN: 1572-882X ;DOI: 10.1007/s10570-016-1036-5

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  • Title:
    Effect of oligosaccharide deposition on the surface of cellulose nanocrystals as a function of acid hydrolysis temperature
  • Author: Bouchard, Jean ; Méthot, Myriam ; Fraschini, Carole ; Beck, Stephanie
  • Subjects: Bioorganic Chemistry ; Bleaching ; Cellulose ; Ceramics ; Chemistry ; Chemistry and Materials Science ; Composites ; Degree of polymerization ; Glass ; Hydrolysis ; Nanocrystals ; Natural Materials ; Oligosaccharides ; Optical properties ; Organic Chemistry ; Original Paper ; Physical Chemistry ; Polymer Sciences ; Sulfuric acid ; Surface properties ; Sustainable Development ; Temperature ; Viscosity
  • Is Part Of: Cellulose (London), 2016-12, Vol.23 (6), p.3555-3567
  • Description: Recent findings indicate there is only a small window of sulfuric acid concentration (60–65 %) and temperature (45–65 °C) which allows efficient extraction of cellulose nanocrystals in significant quantities from bleached chemical pulp. In the present report, we develop a systematic explanation for how hydrolysis temperature, at a specific acid concentration, governs CNC surface properties. We demonstrate that CNCs with different suspension viscosity, stability in electrolyte-containing solutions, and optical properties can be produced, based on the presence or not of a precipitated oligosaccharide layer (OSL) on the surface of the nanocrystals. At hydrolysis temperatures below 65 °C, the degree of polymerization (DP) distribution of cellulose chains in CNC samples exhibits a bimodal distribution, indicating an accumulation of oligosaccharides on the CNC surface which increases as the hydrolysis temperature is decreased. At low hydrolysis temperature (45 °C), the oligosaccharides dissolved in the strong acid phase have a DP between 7 and 20 and precipitate onto CNCs when the reaction is quenched by diluting with water. As the temperature of hydrolysis is increased (50–60 °C), the dissolved oligosaccharides are hydrolyzed faster and their DP decreases such that they remain soluble after quenching. At 65 °C, no precipitated oligosaccharides can be detected on the CNC surface. Based on these results, we propose possible explanations to account for the effects of the OSL on the CNC suspension viscosity and stability and on optical properties of CNC films.
  • Publisher: Dordrecht: Springer Netherlands
  • Language: English
  • Identifier: ISSN: 0969-0239
    EISSN: 1572-882X
    DOI: 10.1007/s10570-016-1036-5
  • Source: AUTh Library subscriptions: ProQuest Central
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