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Rhodium-Catalyzed Asymmetric Hydroformylation of 1,1-Disubstituted Allylphthalimides: A Catalytic Route to [beta] super(3)-Amino Acids

Advanced synthesis & catalysis, 2013-03, Vol.355 (4), p.679-684 [Peer Reviewed Journal]

ISSN: 1615-4150 ;EISSN: 1615-4169 ;DOI: 10.1002/adsc.201200960

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  • Title:
    Rhodium-Catalyzed Asymmetric Hydroformylation of 1,1-Disubstituted Allylphthalimides: A Catalytic Route to [beta] super(3)-Amino Acids
  • Author: Zheng, Xin ; Cao, Bonan ; Liu, Tang-lin ; Zhang, Xumu
  • Subjects: Alcohols
  • Is Part Of: Advanced synthesis & catalysis, 2013-03, Vol.355 (4), p.679-684
  • Description: The high enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted allylphthalimides has been developed. By employing chiral ligand 1,2-bis[(2S,5S)-2,5-diphenylphosp holano]ethane [(S,S)-Ph-BPE], a series of [beta] super(3)-aminoaldehydes can be prepared with up to 95% enantioselectivity. This asymmetric procedure provides an efficient alternative route to prepare chiral [beta] super(3)-amino acids and alcohols.
  • Language: English
  • Identifier: ISSN: 1615-4150
    EISSN: 1615-4169
    DOI: 10.1002/adsc.201200960
  • Source: Alma/SFX Local Collection
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